1Friendly heads-up (before due date)
A few days before the due date - prevents most lateness.
Subject
Invoice [number] due [date] - all good on your end?
Body
Hi [First name], A quick heads-up that invoice [number] for [amount] is due on [due date]. I have attached it again so it is one click away, and you can pay via [payment method/link]. If it is already scheduled - perfect, ignore me. And if anything about the invoice needs correcting to sail through your approval process (PO number, line items, addressee), tell me now and I will turn it around today. Thanks! [Your name]